However, unlike other newcomers they will pose a major threat as they are currently rated number two in the world in the official FIFA rankings.
The only reason they are not one of the top seeds is because of their failure to reach the Finals in the past.
They booked their place in Germany with a play-off win over Norway and will feature plenty of recognisable players such as Milan Baros, Petr Cech and Karel Poborsky.
The Czechs highlighted their potential when they reached the semi-finals of Euro 2004 before losing to eventual champions Greece.
Coach: Karel Bruckner
One to watch: Tomas Rosicky
World ranking: 2
Previous tournaments: 0
Best finish: n/a