They were unbeaten in 12 games and were overall top scorers across the continent with 35.
Surprisingly, this will be only their fourth World Cup, and their best-ever finish came in the 1966 tournament when they were third.
Expect Premiership stars Cristiano Ronaldo, Paulo Ferreira and Ricardo Carvalho to feature.
Manager Luiz 'Big Phil' Scolari was the man who guided Brazil to World Cup victory over England four years ago as the Samba Stars ultimately lifted the trophy.
Coach: Luiz Felipe Scolari
One to watch: Deco
World ranking: 4
Previous tournaments: 3
Best finish: Third place (1966)