That was a massive relief after they had suffered the agony of defeat in the play-offs in attempting to reach the past two tournaments.
In fact, this is their first appearance in any major competition having failed to make it through to the European Championship Finals since they gained independence in 1991.
Coach Oleg Blokhin is a former European Player of the Year and he is also an MP in the Ukrainian parliament which means he needs special dispensation to lead the team in Germany.
England have played Ukraine twice in friendlies, securing two wins with five goals scored and none conceded.
Coach: Oleg Blokhin
One to watch: Andriy Shevchencko
World ranking: 45
Previous tournaments: 0
Best finish: n/a